Environment, Safety, and Health INTEGRATED HAZARD APPRAISAL of BERKELEY LAB
LIFE SCIENCES DIVISION

for Work Definition and Hazards Identification

August 16, 1996




ORGANIZATION AND MANAGEMENT

The Chair of the Life Sciences Division's Environment, Safety & Health Committee reports directly to the Division Director, Mina Bissell or the Deputy Head, Aloke Chatterjee. The chair is Tony Linard, the Safety Officer and Division Safety Coordinator. The committee staff includes a Quality Assurance Officer, a Database Manager and a Self-Assessment Officer. Committee membership is composed of representatives of PIs, staff, and students on a rotating assignment basis. The Division Safety Coordinator (Tony Linard) is charged with oversight of matters pertaining to environment, safety, or health (ES&H). The ES&H Committee meets monthly and provides guidance to the Division Director with regard to ES&H concerns.

Principal investigators (PI) report either directly or through department heads to the Division Director (Mina Bissell) and are accountable for the scientific excellence, relevance to the DOE mission, and fiscal integrity of their programs, as well as adherence to all administrative and regulatory requirements.

For purposes of this hazard analysis, the activities of the Division were grouped into the following organizational units

1. Human Genome Center

2. Subcellular Structure

3. Radiation Biology

4. Cancer Biology

5. Molecular & Nuclear Medicine

6. Functional Imaging

7. Environmental Biotechnology

8. General Support

Operations on the University of California Berkeley (UCB) campus consist of only one activity located in Barker Hall. The work consists of computer modeling.

Approximately 10% of the principle investigators hold faculty positions.

PERFORMANCE EXPECTATIONS AND OBJECTIVES

Research Program Management Responsibility for Safety

Line Management (the Supervisor or Principle Investigator) is responsible for the protection of the public, the workers, and the environment.

At the Berkeley Laboratory the following documents establish the policy and provide the implementation guidance that makes line management effectively accountable for protection of workers, the public and the environment:

Clear Roles and Responsibilities

Clear and unambiguous lines of authority and responsibility for ensuring safety are established and maintained at all organizational levels within the Department and its contractors.

Each Division making up the Berkeley Laboratory has clearly defined lines of responsibility down to the working level. Each division designates a research investigator to represent its views and concerns on the Laboratory Safety Review Committee and a full time employee to act as the ES&H Coordinator. This Coordinator acts as the interface between ES&H concerns and compliance in the workplace and the EH&S technical professionals. The organizational information is updated every 60 days and is retained in the Functional/Facility Notebooks as appropriate (see OAP).

Competence Commensurate with Responsibilities

Personnel possess the experience, knowledge, skills, and abilities that are necessary to discharge their responsibilities.

Job assignments, including hires, are reviewed by line management and by the compensation group within Human Resources to ensure that the requirements and responsibilities of a job are matched by the experience, knowledge and skills of individuals selected for assignment. A performance expectation for managers and supervisors in the Division of Environment, Health and Safety is how well the talents, knowledge and skills of staff are matched to work assignments and responsibilities

The Laboratory's training program ensures that each staff member, including participating guests, is adequately trained to do participate safely in Laboratory activities. Staff, with supervisor participation, fill out the Jobs Hazards Questionnaire (JHQ) describing the hazards associated with their job assignment and work area. Evaluation of the responses by the Training Coordinator and the cognizant supervisor determines the training regimen needed to carry out work in a manner that protects the employee, co-workers, the public and the environment.

Balanced Priorities

Resources are effectively allocated to address safety, programmatic, and operational considerations. Protecting the public, the workers, and the environment is a priority whenever activities are planned and performed.

All environment, safety and health activities in the Laboratory are described in technical terms with budgetary information included. Each year this information is updated, reviewed and prioritized on the basis of risk to workers, public, and the environment by a Laboratory wide committee selected to represent programmatic line management and ES & H professionals. This document is utilized by Laboratory Senior Management in strategically planning the immediate focus and long term goals of the environment, safety and health program at the Laboratory.

Hazard Controls Tailored to Work Being Performed

Administrative and engineering controls to prevent and mitigate hazards are tailored to the work and associated hazards being performed.

Chapter 6 of the Environment, Health and Safety Manual clearly defines the steps for each line manager to develop the appropriate engineering and administrative controls to mitigate hazards in the workplace. The Laboratory's Self Assessment Program, including Functional Appraisals by ES & H professionals, and the UC/DOE Contract 98 Performance Measures provide assurance that implementation of hazards control is adequate to protection the worker, the public and the environment.

Identification of Safety Standards and Requirements

Before work is performed, the associated hazards are evaluated and an agreed-upon set of safety standards and requirements are established which, if properly implemented, provide adequate assurance that the public, the workers, and the environment are protected from adverse consequences.

The Laboratory is dedicated to following the Necessary and Sufficient Closure Process (DOE 450.3) on an iterative basis at all levels of activities in the Laboratory to ensure the Safety Standards are adequate to provide protection to workers, the public and the environment. This process is completed by to commencement of work in those situations where current work is significantly modified, new work is proposed or substantial facility modifications are being made (Chapter 6, Environment Health and Safety Manual).

Operations Authorization

The conditions and requirements to be satisfied for operations to be initiated and conducted are clearly established and agreed-upon.

Conditions and requirements for facilities determined to be of higher risk based on the Preliminary Hazards Analysis are contained in a Safety Analysis Document. Activity Hazard Documents are the basis for meeting this requirement for specific operations and activities falling into the higher risk category at the Berkeley Laboratory. Internal Agreements describing the performance expectations by each party are used for operations between two functional areas where the quality of performance might adversely impact the Laboratory's ability to meet its responsibility to protect workers, the public and the environment.

ACTIONS TO BE PERFORMED

The Life Sciences Division is broadly charged with advancing knowledge of biological processes by investigating mechanisms as intricate as gene expression, and expanding the effort to link biological structure and function. These studies embrace a spectrum of disciplines: molecular cryogenetics; cellular differentiation, growth, and carcinogenesis; hematopoiesis; subcellular and macromolecular structure; diagnostic and functional imaging; radiation biology; nuclear and molecular medicine; and the development of bioinstrumentation. The Division has established a preeminent position in four specific areas of human disease research: coronary artery disease; the biology of breast cancer; metabolic studies of neurological diseases; and disorders of red blood cell formation.

1. Human Genome Center: Research activities include DNA sequencing, genetic mapping, physical mapping, and cDNA isolation and analysis.

2. Subcellular Structure: Research activities include the study of the molecular structure and subcellular organization of proteins related to the cytoskeleton and various cell membranes through the use of electron crystallography and x-ray crystallography including electron microscopy, UV-confocal light microscopy, soft x-ray microscopy, and related techniques.

3. Radiation Biology: Research activities include the study of the effects of radiation on cells including radiation-induced cell damage during travel in outer space. Research activities include the study of the regulation and function of oncogenes and tumor suppressor genes in cultured human and rodent cells, and in transgenic mice. Mammary gland biology is studied in culture and in transgenic mice. Rodent and human cells in culture and in vivo are studied. DNA damage due both to radiation in natural and occupational environments, and to natural chemicals in the diet, is investigated. The molecular mechanisms of DNA repair and its role in mitigating these risks is also studied.

4. Cancer Biology: Research activities include study of the molecular mechanisms of breast cancer including of normal cellular growth and differentiation distinguishing normal human breast cells from their malignant counterparts.

5. Molecular and Nuclear Medicine: The goal of this program is the understanding of the role of lipoproteins in the development of atherosclerosis and coronary disease, specifically to study the genetic and cellular mechanisms that regulate their metabolism. Procedures utilized include isotopic tracer studies, human genetic linkage analysis, creation, use and analysis of transgenic animal models, analysis of interaction between oxidative stress, lipoprotein metabolism, and the induction of atherosclerosis, and numerous clinical studies to examine how diet, drugs, exercise and hormones effect the regulation of atherogenic lipoproteins.

6. Center for Functional Imaging (CFI): The goal of CFI is to develop the technology and procedures for the non-invasive imaging of humans, and to utilize these techniques to study the physiology of normal and disease states in humans and animals. Activities include the design and construction of positron emission tomography (PET) and nuclear magnetic resonance (MRI) hardware and software, the development and application of new data analysis procedures, the design and synthesis of new radiotracer agents for use in PET and single photon emission computed tomography (SPECT), the biological testing of these new radiopharmaceuticals, and their application in animal and human medical research. The center operates 2 PET machines, 1 SPECT machine, 2 MRI machines, and 1 biomedical cyclotron.

7. Environmental Biotechnology: Research activities consist of microbiology and molecularbiology research on materials and organisims which occur naturally in the environment. The Environmental Biotechnology is a multi-divisional unit which collaborates with the Earth Sciences Division in research activities.

8. General Support: LSD contains on Irradiator in Building 74 which is available for use by all departments in the division. LSD personnel oversee the LBNL Animal Facilities.

PHYSICAL CONDITIONS

WITHIN WHICH THE WORK WILL BE PERFORMED

Building 1 Donner Hall

Donner Hall is a four-story building located on the University of California, Berkeley campus. The building consists of laboratory space with adjacent offices. The Life Sciences Division occupies the entire building except for a small portion occupied by the University of California. The following departments have research activities in the building: Molecular & Nuclear Medicine, Subcellular Structure and Cancer Biology.

Building 29

Life Sciences Division occupies a portion of the second floor. The spaces consist of primarily offices with some computer research.

Building 55 Complex

The Building 55 complex consists of Center for Functional Imaging activities. Building 55 contains laboratories and adjacent offices. Building 55A contains a Nuclear Magnetic Resonance Imaging facility. The trailer 55B is used for offices and computer research.

Building 56

Building 56 is the Biomedical Isotope Facility and contains a mini-accelerator used for the synthesis of radiopharmaceuticals.

Building 64

B64 is a two story building with Life Science Division laboratories and offices. The fist floor contains laboratories occupied by the Human Genome Center. The second floor contains offices and unoccupied laboratory space which is currently being modified to contain additional Human Genome Laboratories.

Building 70A

Radiation Biology and Cancer Biology laboratories and offices occupy a portion of the first floor of Building 70A. In addition, a small portion of the 4th Floor is occupied by some Radiation Biology and Environmental Biotechnology departments.

Building 74: Building 74 is completely occupied by the Life Sciences Division. The departments include: Radiation Biology, Cancer Biology and the Human Genome Project. In addition the building contains an Irradiator used by the entire division

Building 83: Building 83 and 83B are occupied completely by the Cancer Biology Department.

Building 934: Building 934 is located off-campus and is occupied completely by the Life Sciences Division. Laboratory and offices areas include Radiation Biology, Cancer Biology, Molecular and Nuclear Medicine and some equipment used by the Human Genome Center. In addition, one room is managed by the EH&S Waste Management Department.

Building 940: Building 940 is located in the City of Berkeley. It is technically not a part of LBNL., but is leased by Sequoia Hospital District to house the Cholesterol Research medical facility; it is a state regulated medical facility. The facility includes space used for offices, as well as medical facilities. Radioactive materials and hazardous chemicals are not employed in this building.

MATERIALS AND CONDITIONS

THAT COULD CAUSE ADVERSE CONSEQUENCES

GENERAL

The Life Sciences Division (LSD) includes approximately 150 laboratories in which hazardous chemicals are used. Several of the laboratories make use of non-ionizing radiation sources, lasers, cold rooms, magnetic fields and noisy equipment. A number of laboratories use biohazardous agents, including human cell lines, human blood products and pathogens. Most laboratories perform high voltage or low voltage electrophoresis and centrifugation. Small vacuum systems and compressed gasses are used widely throughout LSD.

Electrical and Mechanical Hazards:
A limited array of electrical and mechanical hazards are present in the LSD. These include high voltage electrical systems, repetitive trauma associated with office work, a few small vacuum systems, autoclaves, some pressurized gas systems, belt driven equipment, centrifuges, ovens and robots.

Electrical Hazards

The primary electrical hazard associated with LSD is the use of high voltage electrophoresis equipment. Electrophoresis is found in most laboratories in LSD.

The overall level of concern associated with high voltage equipment is moderate. This arises because of the exposed connectors and surfaces on electrophoresis equipment.

High voltage power supplies are also associated with other equipment, such as laser systems.

There are few high amperage systems in LSD. High current is provided to a couple pieces of equipment, notably the MRI equipment in building 55A.

Pressure and Vacuum Hazards

The overall level of concern associated with pressure and vacuum systems in LSD is low.

The main pressure hazards are the compressed gas cylinders, mostly nitrogen, oxygen, argon and carbon dioxide.

There are no significant pressure systems in LSD.

There are a few glass systems that are filled from a compressed gas cylinder.

Vacuum systems are limited to small bell jar systems and low vacuum ovens. The ovens often possess glass windows larger than 4 inches in diameter.

Several buildings are equipped with small to moderate sized steam autoclave systems.

Ovens

The overall level of concern associated with the use of ovens in LSD is very low.

Low temperature (<100 degrees C) ovens are widely used in LSD.

Centrifuges

The level of concern associated with the use of centrifuges is low in LSD.

Dozens of ultracentrifuges and many more small centrifuges are used in LSD facilities.

Robots

Mechanical robots, programmed to repeat recurring tasks such as pipetting, are used in several areas in LSD. The hazard associated with the use of these robots is judged to be low.

Repetitive Mechanical Trauma

Office operations include the usual array of ergonomic issues, notably those associated with the use of computers and workstations.

Chemical Hazards:
A variety of toxic, flammable, corrosive, reactive or otherwise dangerous chemicals are used in the LSD. In almost all cases, the quantities used at any time are quite small, consistent with typical biochemical laboratory operations. Examples of hazardous chemicals in use in LSD are provided below. None of the LSD facilities use toxic cryogens or flammable cryogens.

Flammable Gases:

The level of concern relating to the use of flammable gasses in LSD is essentially nil.

Flammable gases are not widely used in LSD. Only one cylinder of compressed hydrogen was identified in a laboratory. Very small cylinders of compressed carbon monoxide are used in several labs.

Flammable Liquids:

The level of concern associated with the use of flammable liquids in LSD is low overall.

Flammable liquids are used throughout LSD in smaller quantities.

Fourteen rooms were identified as having a moderate level of concern associated with flammable liquids, in all cases because the quantities in storage.

Typical flammable liquids include ethyl alcohol, isopropyl alcohol, toluene and acetone.

Inert Cryogens:

The level of concern associated with the use of inert cryogens is low.

Liquid nitrogen is used widely in dewers up to 160L.

Several labs have dewers directly plumbed to experimental apparatus or equipment.

Corrosives:

The level of concern associated with the use of corrosives in LSD is low overall, with eleven labs identified as representing a "moderate" level of concern.

Most of the LSD laboratories store or use small amounts of corrosive materials.

Common corrosives include glacial acetic acid, hydrochloric acid, phenol and sodium hydroxide.

Reactives:

The level of concern associated with the use of reactives in LSD is low overall, with only two labs identified as representing a moderate level of concern

Small amounts of reactive chemicals are used in about 30% of the laboratories in LSD.

Common reactive chemicals include sodium azide, hydrazine, phosphorous pentachloride and glacial acetic acid.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins in LSD is low.

No labs were identified with a level of concern of moderate to high.

Common reproductive toxins include lead compounds and toluene.

Dibromochloropropane and ethylene oxide were identified in a few laboratories

Carcinogens:

The overall level of concern associated with the use of carcinogens in LSD is low.

Seven labs were identified as representing a moderate level of concern with respect to carcinogens. This was usually triggered by the number of different carcinogens in use rather than a large quantity of any one carcinogen.

Small quantities of organic carcinogens such as methylene chloride, chloroform, benzene, acrylamide and carbon tetrachloride are used.

Similarly, small quantities of inorganic carcinogens such as arsenic, cadmium, lead acetate and chromium trioxide are used inside hoods.

Pyrophorics:

The overall level of concern associated with the use of pyrophorics in LSD is extremely low.

True pyrophorics were only identified in a few labs, and none of these were pyrophoric gasses.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials in LSD is low.

No labs were identified as having a moderate or high level of concern associated with the use or storage of toxic materials.

Typical inorganic toxic compounds include arsenic compounds, lithium salts, selenium and antimony.

Typical organic toxic compounds include methanol, formaldehyde and phenol.

Typical highly toxic chemicals include cyanide salts and cholera toxin.

Health Hazard Gases:

The overall level of concern associated with health hazard gasses in LSD is very low.

Very few toxic gases are used in LSD. Toxic gases were only found in three buildings and a total of 3 lab rooms.

Toxic gases in use include nitrous oxide, carbon monoxide, fluorine and hydrogen chloride. Only Building 56 uses fluorine. Of these, only nitrous oxide is present in significant quantities.

Oxidizers:

The overall level of concern associated with the use of oxidizers in LSD is low.

No laboratories were identified as having a moderate level of concern associated with oxidizers.

Approximately 30% of the laboratories store or use oxidizers.

Typical oxidizers include compressed oxygen, nitric acid, hydrogen peroxide and bleach.

Physical Agents:
Physical agents present in LSD include ultraviolet radiation, cold, lasers, noise and microwave radiation. Each of these is discussed below.

Ultraviolet Radiation

The overall level of concern associated with the use of ultraviolet radiation in LSD is low. Two facilities were identified where the level of concern is judged to be moderate. These are entire rooms which are bathed in UV-B radiation from quartz-mercury lamps.

Ultraviolet sources are used widely in LSD, both as a germicidal treatment and as an imaging tool for fluorescent molecules.

Radiofrequency/Microwave Radiation

The overall level of concern associated with the use of radiofrequency/microwave radiation in LSD is low.

The only use of RF/MW besides commercial food-type ovens are two MRI machines in building 55A.

Cold

The overall level of concern associated with the use of cold work rooms in LSD is low.

Several laboratories have refrigerated rooms in which work is conducted, typically HPLC. Some of these are operated as sub-freezing temperatures.

Lasers

The overall level of concern associated with the use of lasers in LSD is low.

Most of the lasers in use are very low power units.

There are only a couple of class 3 or class 4 lasers in use.

Noise

The overall level of concern associated with noise in the LSD is low.

The primary source of noise exposure is the use of ultrasonic cell disrupters.

Ear muffs were located at the point of use of all ultrasonicators.

Magnetic Fields

The overall level of concern associated with the use of magnetic fields in LSD is very low. Strong DC magnetic fields are present in only two places, where MRI machines are used.

Infectious/Biohazardous Agents
The LSD uses a number of known or potentially biohazardous materials, including human liver and breast cell lines, human blood fractions, animal cell lines, vaccinia virus, malarial agent, and bacteria. Biosafety cabinets are used in several areas within LSD.

The overall level of concern associated with the use of these biohazardous agents in LSD is low.

None of these operations exceeds Biohazard Level 2.

Many of the cell lines are pre-screened to exclude common pathogens.

Personnel that handle unscreened human blood products have generally been provided with the hepatitis B vaccine series.

Work with the potential to generate infectious aerosols is conducted in either a fume hood or a biosafety cabinet.

UV lamps are used extensively to sterilize biosafety cabinets and rooms in which biohazardous agents are used.

X-Ray Machines:
Five X Ray machines were located. Two in the Radiation Biology Department (B74-152 and B70A-1103). One in the Center for Functional Imaging (55-200). One in Molecular & Nuclear Medicine (B1-305). And, one in Subcellular Structure (1-259c). All are evaluated to be low hazard. The machine in Building 74 is enclosed in a shielded room.

Accelerators and Radiation:
LSD has two types of activities which have radiation hazards. Research and development uses radio labeled tracers in biochemical research applications. In addition, LSD has a mini-cyclotron which has direct radiation hazards.

Radio labeled tracers:
Radiolabeled tracers are used in bench top work using standard biochemical methods. Positron emitters are injected into human patients and animals for Positron Emission Tomography (PET) studies. Quantities used are microcurie to approximately 10 millicuries. Examples include P-32, C-14, H-3 (beta emitters) and F-18 positron (gamma emitter).

Accelerator:
The mini-cyclotron is located in Building 56 and is an 11MeV proton accelerator used to produce positron emitting radioisotopes. The positron emitters are used in shielded gloveboxes for the production of radiopharmaceuticals. The mini-cyclotron is a commercial unit with self contained shielding and, in addition, is located in a shielded room.

Effluent from research activities and the accelerator is monitored according to NESHAPS requirements.

PROGRAM SPECIFIC FINDINGS

(Chemical, Physical and Biohazardous Agents)

Mechanical and electrical hazards are very uniform and routine throughout the LSD. The general outline of these safety issues is sufficient to characterize the Division. However, there is a wider range and a larger number of chemical, physical and biohazardous agents that are used in LSD. Thus, chemical, physical and biohazardous agents will be characterized by operational organization within LSD.

1. Human Genome Center: The Human Genome Center (HGC) are located in buildings 64 and 74 with minor support equipment in 934.

Chemical Hazards

Flammable Gases:

There are essentially no compressed flammable gases used in the HGC.

Flammable Liquids:

The level of concern associated with the use of flammable liquids is low overall.

No labs were found to pose a moderate level of concern with respect to flammable liquids.

Flammable liquids are used throughout HGC in smaller quantities.

Typical flammable liquids include ethyl alcohol, isopropyl alcohol, toluene and acetone.

Inert Cryogens:

The level of concern associated with the use of inert cryogens is low.

Cryogens are used in a number of labs in building 74 and 934.

Several labs have dewers directly plumbed to experimental apparatus or equipment.

Corrosives:

The level of concern associated with the use of corrosives in HGC is low overall.

About 1/3 of the labs use significant amounts of corrosive materials.

Common corrosives include glacial acetic acid, hydrochloric acid and sodium hydroxide.

Reactives:

The level of concern associated with the use of reactives in the HGC is low overall.

No laboratories were designated as having a moderate level of concern with respect to reactive chemicals.

Approximately 1/4 of the labs in the HGC use significant amounts of reactive chemicals.

Common reactive chemicals include sodium azide and glacial acetic acid.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins in the HGC is low.

No labs were identified with a level of concern of moderate.

Approximately 1/4 of the labs in the HGC use or store reproductive toxins.

Common reproductive toxins include lead compounds and toluene.

Carcinogens:

The overall level of concern associated with the use of carcinogens in the HGC is low.

One lab was designated as posing a moderate level of concern with respect to the use and storage of carcinogens (building 74, room 3050). This lab has substantial quantities of chloroform and formaldehyde, as well as acrylamide, cadmium sulfate and chloramphenicol.

Small quantities of organic carcinogens such as methylene chloride, formaldehyde, chloroform and acrylamide are used.

Similarly, small quantities of inorganic carcinogens such as chrome (IV), cadmium, arsenic compounds and lead acetate are used.

Pyrophorics:

The overall level of concern associated with the use of pyrophorics in the HGC is nil.

There are essentially no pyrophoric materials used in the HGC.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials in the HGC is low.

No labs were identified as having a moderate or high level of concern associated with the use or storage of toxic materials.

Typical inorganic toxic compounds include arsenic compounds, lithium salts and cadmium compounds.

Typical organic toxic compounds include methanol, formaldehyde and ethidium bromide.

Typical highly toxic chemicals include cyanide salts.

Health Hazard Gases:

The overall level of concern associated with health hazard gasses in the HGC is Nil.

There is no use or storage of health hazard gasses in any significant quantity in the HGC.

Oxidizers:

The overall level of concern associated with the use of oxidizers in the HGC is extremely low.

Only one lab was found to use or store significant quantities of oxidizers (nitric acid, building 64, room 128). However, several labs used small quantities of bleach.

Typical oxidizers include nitric acid hydrogen peroxide and bleach.

Physical Agents

Physical agents present in the HGC include ultraviolet radiation, lasers, noise and microwave radiation. Each of these is discussed below.

Ultraviolet Radiation

The overall level of concern associated with the use of ultraviolet radiation in the HGC is low.

Ultraviolet sources are used widely in the HGC, both as a germicidal treatment and as an imaging tool for fluorescent molecules. Only one piece of equipment has been user-modified.

Radiofrequency/Microwave Radiation

The overall level of concern associated with the use of radiofrequency/microwave radiation in the HGC is extremely low.

The only use of RF/MW is in commercial food-type ovens, which are used to prepare media. There is no laboratory type or locally built RF/MW sources.

Lasers

The overall level of concern associated with the use of lasers in the HGC is very low.

Only three rooms contain lasers.

Noise

The overall level of concern associated with noise in the HGC is low.

The primary source of noise exposure is the use of ultrasonic cell disrupters.

Ear muffs were located at the point of use of all ultrasonicators.

Infectious/Biohazardous Agents

Biosafety cabinets are not used in this program.

Human Blood/Blood Products

The level of concern associated with the use of human blood products is very low.

A couple of labs use human blood products, notably immunoglobulin G. This blood product is screened for major pathogens (HIV, HBV) and processed to remove most other pathogens. However, it is still possible that immunoglobulin products contain pathogenic viruses (e.g., HCV).

Cell Culture (non-pathogenic)

The level of concern associated with the use of cell cultures in the HGC is very low.

Cell culture work is limited to the use of non-infected mouse cell lines.

Pathogens

Pathogenic organisms are not intentionally used in the HGC.

2. SubCellular Structure Program: The Subcellular Structure (SS) program is located in Building 1 (Donner Hall).

Chemical Hazards

Flammable Gases:

There are essentially no compressed flammable gasses used in the SS.

Flammable Liquids:

The level of concern associated with the use of flammable liquids is low overall.

Most of the labs in the SS use very small quantities of flammable liquids.

No labs were found to pose a moderate level of concern with respect to flammable liquids.

Typical flammable liquids include ethyl alcohol, hexane, butanol and acetone.

Inert Cryogens:

The level of concern associated with the use of inert cryogens is low.

Cryogens are used in six labs.

Cryogens are not present in cold traps or piped systems.

Corrosives:

The level of concern associated with the use of corrosives in SS is low overall.

Only a few of the laboratory areas use significant amounts of corrosive materials.

No laboratories were judged to pose a moderate level of concern with respect to corrosive materials.

Common corrosives ammonium hydroxide, calcium hydroxide, hydrobromic acid, sodium hydroxide.

Reactives:

The level of concern associated with the use of reactives in SS is low overall.

No laboratories were designated as having a moderate to high level of concern with respect to reactive chemicals.

Only a few labs in the SS use reactive chemicals.

Common reactive chemicals include various nitrates, hydrazine and sodium azide.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins in SS is low.

Only a few of the labs in the SS store or use reproductive toxins.

Common reproductive toxins include sodium bromide, lead compounds and colchcine.

Carcinogens:

The overall level of concern associated with the use of carcinogens in the SS is low.

No labs were identified with a level of concern of moderate to high.

Small quantities of organic carcinogens such as benzene, methylene chloride, formaldehyde, chloroform and acrylamide are used.

Pyrophorics:

The overall level of concern associated with the use of pyrophorics in the SS is nil.

Pyrophorics are not used in the SS labs.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials in the SS is low.

No labs were identified as having a moderate or high level of concern associated with the use or storage of toxic materials.

Approximately 1/4 of the laboratory areas use or store toxic materials.

Typical inorganic toxic compounds include phosphorus pentoxide, arsenic compounds and lithium salts.

Typical organic toxic compounds include methanol and formaldehyde.

Typical highly toxic chemicals include cyanide compounds.

Health Hazard Gases:

The overall level of concern associated with health hazard gasses in the SS is nil.

There are no toxic gases used in any quantity in the SS.

Oxidizers:

The overall level of concern associated with the use of oxidizers in the SS is low.

Only a few of the laboratories in SS store or use oxidizers.

Typical oxidizers include hydrogen peroxide.

Physical Agents

Physical agents present in the SS include noise and cold. Each of these is discussed below.

Noise

The overall level of concern associated with exposure to noise is very low.

Only one room (333) was judged to have a noise concern.

Cold

The overall level of concern with cold is very low.

The SS operates four work-in cold rooms. Some of these are operated at freezing temperatures.

Infectious/Biohazardous Agents

Biohazardous agents and biosafety cabinets are used in this program. None of the work exceeds biosafety level 2.

Human Blood/Blood Products

The overall level of concern associated with the use of human blood products is nil.

Cell Culture (non-pathogenic)

Cell cultures are used in the SS.

Pathogens

The Vaccina virus is used in room 331.

3. Radiation Biology: Radiation Biology (RB) laboratories are located in buildings 70A, 74 and 934.

Chemical Hazards

Flammable Gases:

There are essentially no compressed flammable gasses used in RB.

Flammable Liquids:

The level of concern associated with the use of flammable liquids is low.

No labs were found to pose a moderate level of concern with respect to flammable liquids.

Flammable liquids are used throughout RB in smaller quantities.

Typical flammable liquids include methyl alcohol, ethyl alcohol, isopropyl alcohol, xylene and acetone.

Inert Cryogens:

The level of concern associated with the use of inert cryogens is low.

Cryogens are used in a number of labs in each building.

There are no cold traps or piped cryogen sources in RB.

Corrosives:

The level of concern associated with the use of corrosives in RB is low.

About 1/2 of the labs use significant amounts of corrosive materials.

Common corrosives include bleach, glacial acetic acid, hydrochloric acid, phenol and sodium hydroxide.

Reactives:

The level of concern associated with the use of reactives in RB is low.

No laboratories were designated as having a moderate level of concern with respect to reactive chemicals.

Common reactive chemicals include sodium azide and glacial acetic acid.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins in RB is low.

No labs were identified with a level of concern of moderate.

Common reproductive toxins include lead compounds, cycloheximide and toluene.

Carcinogens:

The overall level of concern associated with the use of carcinogens in RB is low.

No labs were determined to pose a moderate or high level of concern with respect to the use of carcinogens.

Small quantities of organic carcinogens such as formaldehyde, chloroform and acrylamide are used.

Similarly, small quantities of inorganic carcinogens such as chrome (IV) and arsenic compounds are used.

Pyrophorics:

The overall level of concern associated with the use of pyrophorics in RB is nil.

There are essentially no pyrophoric materials used in RB.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials in RB is low.

No labs were identified as having a moderate or high level of concern associated with the use or storage of toxic materials.

Typical inorganic toxic compounds include arsenic compounds, lithium salts and cadmium compounds.

Typical organic toxic compounds include methanol, formaldehyde and ethidium bromide.

Typical highly toxic chemicals include cyanide salts.

Health Hazard Gases:

There is no use or storage of health hazard gasses in any significant quantity in RB.

The overall level of concern associated with health hazard gasses in RB is Nil.

Oxidizers:

The overall level of concern associated with the use of oxidizers in RB is extremely low.

Only one lab was found to use or store significant quantities of oxidizers (hydrogen peroxide, nitric acid in building 74, room 166). However, several labs used small quantities of bleach and dilute hydrogen peroxide.

Typical oxidizers include nitric acid, hydrogen peroxide and bleach.

Physical Agents

Physical agents present in RB include ultraviolet radiation, noise and microwave radiation. Each of these is discussed below.

Ultraviolet Radiation

The overall level of concern associated with the use of ultraviolet radiation in the RB is low.

Ultraviolet sources are used in the RB as an imaging tool for fluorescent molecules.

There is one user-modified UV unit in use, in building 934, room 32.

Radiofrequency/Microwave Radiation

The overall level of concern associated with the use of radiofrequency/microwave radiation in RB is extremely low.

The only use of RF/MW is in commercial food-type ovens, which are used to prepare media. There are no laboratory type or locally built RF/MW sources.

Noise

The overall level of concern associated with noise in RB is very low.

The primary source of noise exposure is the use of several ultrasonic cell disrupters.

Ear muffs were located at the points of use of the ultrasonicators.

Infectious/Biohazardous Agents

Biohazardous agents and biosafety cabinets are used in this program.

Human Blood/Blood Products

The overall level of concern associated with the use of human blood products is nil.

Human blood products are not used.

Cell Culture (non-pathogenic)

The level of concern associated with the use of cell cultures in RB is low to moderate.

Cell culture work is limited to the use of human cell lines in building 70A, rooms 115, 119, 1121C, and in building 934. Most of the cell lines are commercial and have been screened for common pathogens.

Animal cell lines are used in building 74 room 166.

Pathogens

Pathogenic organisms are not intentionally used in RB.

4. Cancer Biology: Cancer biology laboratory activities are located in Buildings 1, 70A, 74, 83 and 934.

Chemical Hazards

Flammable Gases:

There are essentially no compressed flammable gases used in CB.

Flammable Liquids:

The level of concern associated with the use of flammable liquids is low to moderate overall.

Five labs were found to pose a moderate level of concern with respect to flammable liquids (70A, room 1105, 74 rooms 265 and 252, 934 room 11 and 83 room 110).

Typical flammable liquids include methyl alcohol, ethyl alcohol, toluene and acetone.

Inert Cryogens:

The level of concern associated with the use of inert cryogens is low.

Cryogens are used in a number of labs.

Cold traps or piped cryogen is used in building 83, 70A and 74

Corrosives:

The level of concern associated with the use of corrosives in CB is low overall.

About 1/2 of the labs use significant amounts of corrosive materials.

In two areas (building 83, room 110 and building 934 room 11) the use of corrosives was judged to pose a moderate concern.

Common corrosives include bleach, glacial acetic acid, ammonium hydroxide, hydrochloric acid, sulfuric acid, phenol and sodium hydroxide.

Reactives:

The level of concern associated with the use of reactives in CB is low.

No laboratories were designated as having a moderate level of concern with respect to reactive chemicals.

Approximately 1/3 of the labs in CB use significant amounts of reactive chemicals.

Common reactive chemicals include sodium azide and glacial acetic acid.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins in RB is low.

No labs were identified with a level of concern of moderate.

Approximately 1/4 of the labs in the CB use or store reproductive toxins.

Common reproductive toxins include cycloheximide and toluene.

Carcinogens:

The overall level of concern associated with the use of carcinogens in RB is low.

One lab (building 83, room 110) was determined to pose a moderate level of concern with respect to the use of carcinogens. This lab uses or stores large quantities of chloroform as well as other carcinogens.

Small quantities of organic carcinogens such as formaldehyde, chloroform and acrylamide are used in many areas.

Very little in the way of inorganic carcinogens are used in CB.

Pyrophorics:

The overall level of concern associated with the use of pyrophorics in CB is nil.

There are essentially no pyrophoric materials used in CB.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials in CB is low.

No labs were identified as having a moderate or high level of concern associated with the use or storage of toxic materials.

Typical inorganic toxic compounds include cobalt compounds and lithium salts.

Typical organic toxic compounds include methanol, formaldehyde and ethidium bromide.

One lab was identified as storing or using a highly toxic material, a cyanide salt.

Health Hazard Gases:

There is no use or storage of health hazard gasses in any significant quantity in CB.

The overall level of concern associated with health hazard gasses in CB is nil.

Oxidizers:

The overall level of concern associated with the use of oxidizers in CB is extremely low.

Typical oxidizers include hydrogen peroxide and bleach.

Physical Agents

Physical agents present in CB include ultraviolet radiation, lasers, noise and microwave radiation. Each of these is discussed below.

Ultraviolet Radiation

The overall level of concern associated with the use of ultraviolet radiation in the CB is low.

Ultraviolet sources are used in the CB as an imaging tool for fluorescent molecules.

Two rooms were identified where there are user-modified UV emitting devices (building 1, room 305 and building 934, room 38).

Radiofrequency/Microwave Radiation

The overall level of concern associated with the use of radiofrequency/microwave radiation in CB is extremely low.

The only use of RF/MW is in commercial food-type ovens, which are used to prepare media. There are no laboratory type or locally built RF/MW sources.

Lasers

The overall level of concern associated with the use of lasers in CB is low.

Only one significant laser system is present in building 74, room 235. This operation is covered by an AHD.

Noise

The overall level of concern associated with noise in CB is very low.

The primary source of noise exposure is the use of an ultrasonic cell disrupters.

One or more sonicator is present in buildings 934, 74 and 83.

Ear muffs were located at the point of use of the ultrasonicator.

Infectious/Biohazardous Agents

Biohazardous agents and biosafety cabinets are used in this program.

Human Blood/Blood Products

The overall level of concern associated with the use of human blood products is moderate.

Whole human blood as well as blood fractions are used in the malaria experiments in building 74 room 252. Staff has been vaccinated with hepatitis vaccine.

Cell Culture (non-pathogenic)

The level of concern associated with the use of cell cultures in CB is low.

Human mammary cells (non-transformed) are used in experiments in building 934 room 11. These cells are obtained from reductive mammoplasty surgery and are not screened for pathogens.

Non-pathogenic E-coli cells are cultured in building 74, room 265.

Work does not exceed biosafety level 2.

Pathogens

The malarial agent, plasmodium cynomologi, is used in building 74, room 252.

5. Molecular and Nuclear Medicine: Molecular and Nuclear Medicine (MNM) laboratories are located in Buildings 1 and 934.

Flammable Gases:

The level of concern relating to the use of flammable gasses in MNM is low.

Only one cylinder of compressed hydrogen was identified in a laboratory (room 261).

Flammable Liquids:

The level of concern associated with the use of flammable liquids in MNM is moderate overall.

Flammable liquids are used throughout MNM in smaller quantities.

Several rooms were identified as having a moderate level of concern associated with flammable liquids .

Typical flammable liquids include ethyl alcohol, isopropyl alcohol, hexane and acetone.

Inert Cryogens:

The level of concern associated with the use of inert cryogens is low.

There are no cold traps or cryogens in piping in the MNM.

Corrosives:

The level of concern associated with the use of corrosives in MNM is low overall.

No labs were determined to pose a moderate or high level of concern with respect to corrosive chemicals.

Common corrosives include glacial acetic acid, hydrochloric acid, sulfuric acid and sodium hydroxide.

Reactives:

The level of concern associated with the use of reactives in MNM is low overall.

No labs were judged to pose a moderate or high level of concern with respect to reactive chemicals.

Common reactive chemicals include osmium tetraoxide, nitrate compounds, sodium azide and glacial acetic acid.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins in MNM is low.

No labs were identified with a level of concern of moderate of high.

Common reproductive toxins include lead compounds and toluene.

Carcinogens:

The overall level of concern associated with the use of carcinogens in MNM is low.

No labs were identified as representing a moderate level of concern with respect to carcinogens.

Small quantities of organic carcinogens such as methylene chloride, propylene oxide, chloroform, benzene, acrylamide and ethylene dichloride are used.

Similarly, small quantities of inorganic carcinogens such as arsenic, lead acetate and potassium dichromate are used inside hoods.

Pyrophorics:

The overall level of concern associated with the use of pyrophorics in MNM is nil.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials in MNM is low.

No labs were identified as having a moderate or high level of concern associated with the use or storage of toxic materials.

Typical inorganic toxic compounds include arsenic compounds and lithium salts.

Typical organic toxic compounds include methanol.

Typical highly toxic chemicals include cyanide salts.

Health Hazard Gases:

The overall level of concern associated with health hazard gasses in MNM is nil.

Oxidizers:

The overall level of concern associated with the use of oxidizers in MNM is very low.

No laboratories were identified as having a moderate level of concern associated with oxidizers.

Typical oxidizers include sulfuric acid and nitric acid,

Physical Agents

The only physical agents present in MNM are noise, associated with the use of an untrasonicator in rooms 260 and 267, and cold associated with one cold room (room 117).

Infectious/Biohazardous Agents

Biohazardous agents and biosafety cabinets are used in the MNM.

The overall level of concern associated with the use of these biohazardous agents in MNM is low.

None of these operations exceeds Biohazard Level 2.

Personnel that handle unscreened human blood products have generally been provided with the hepatitis B vaccine series.

Work with the potential to generate infectious aerosols is conducted in either a fume hood or a biosafety cabinet.

UV lamps are used extensively to sterilize biosafety cabinets and rooms in which biohazardous agents are used.

Human Blood/Blood Products

The overall level of concern associated with the use of human blood products is low.

Human blood plasma fractions are used in several of the laboratories.

Cell Culture (non-pathogenic)

The level of concern associated with the use of cell cultures is low.

A human liver cell line use cultured in room 373A.

Work does not exceed biosafety level 2.

Pathogens

No pathogens are intentionally used in the MNM.

6. Center For Functional Imaging: The Center for Functional Imaging (CFI) is located in buildings 55, 55A, 55C and 56.

Chemical Hazards

Flammable Gases:

There are essentially no compressed flammable gasses used in the CFI. Several oxidizing gases, as discussed in the section on health hazard gases, are in use.

Flammable Liquids:

The level of concern associated with the use of flammable liquids is low to moderate overall.

Over 90% of the labs in the CFI use flammable liquids.

Five labs were found to pose a moderate level of concern with respect to flammable liquids (building 55 rooms 127, 135, 151, 208 and 214).

Typical flammable liquids include ethyl alcohol, hexane, MEK, toluene, dioxane and acetone.

Inert Cryogens:

The level of concern associated with the use of inert cryogens is low.

Cryogens are used in a number of labs but stored on the loading dock.

Cryogens are present in cold traps or piped systems.

Corrosives:

The level of concern associated with the use of corrosives in CFI is low to moderate overall.

About 90% of the labs use significant amounts of corrosive materials.

Three laboratories were judged to pose a moderate level of concern with respect to corrosive materials (building 55 rooms 151, 208 and 214).

Common corrosives include ammonium hydroxide, hydroiodic acid, nitric acid, perchloric acid, hydrochloric acid, sulfuric acid and sodium hydroxide.

Reactives:

The level of concern associated with the use of reactives in CFI is moderate overall.

One laboratory was designated as having a moderate to high level of concern with respect to reactive chemicals. This room, 208 in building 55, stores and uses materials such as potassium superoxide, potassium metal, sodium azide, lithium metal, sodium ethoxide and sodium peroxide. An AHD covers the safety issues with sodium azide.

Common reactive chemicals include perchloric acid, potassium t-butoxide, titanium tetrachloride, titanium isopropoxide, lithium aluminum hydride and sodium azide.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins in CFI is low.

Approximately 1/3 of the labs in CFI use or store reproductive toxins.

Common reproductive toxins include lead compounds, carbon disulfide and toluene.

Carcinogens:

The overall level of concern associated with the use of carcinogens in the CFI is moderate.

One lab was identified with a level of concern of moderate to high (room 214 in building 55). This room uses or stores relatively large quantities of benzene, ethylene oxide, propylene oxide, ethylene dichloride and other organic carcinogens.

Small quantities of organic carcinogens such as benzene, DMF, ethylene oxide, methylene chloride, formaldehyde, chloroform and acrylamide are used.

Little in the way of inorganic carcinogens are used in CFI. Small amounts of cadmium and chromium (IV) compounds can be found in a few laboratories.

Pyrophorics:

The overall level of concern associated with the use of pyrophorics in the CFI is low.

Small quantities of air/water reactive alkali metals are used in several labs.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials in the CFI is low.

No labs were identified as having a moderate or high level of concern associated with the use or storage of toxic materials.

Approximately 3/4 of the laboratory areas use or store toxic materials.

Typical inorganic toxic compounds include antimony compounds, phosphorus pentoxide, arsenic compounds, lithium salts and cadmium compounds.

Typical organic toxic compounds include carbon disulfide, methanol, formaldehyde.

Typical highly toxic chemicals include cyanide compounds.

Health Hazard Gases:

The overall level of concern associated with health hazard gasses in the CFI is low.

The slightly toxic gas nitrous oxide is present in large quantities in building 55, room 139. The level of concern associated with toxic gases in this operation is moderate. Minute quantities of bottled carbon monoxide are present in several other areas. Small quantities of ammonia and hydrogen chloride are used in building 55 room 151. Fluorine gas is present in building 56 room 100.

Oxidizers:

The overall level of concern associated with the use of oxidizers in the CFI is low.

Approximately 1/2 of the laboratory areas store or use oxidizers.

Typical oxidizers include hydrazine, nitric acid, and hydrogen peroxide. Fluorine gas, a strong oxidizer, is present in one lab.

Physical Agents

Physical agents present in the CFI include magnetic fields and microwave radiation. Each of these is discussed below.

Radiofrequency/Microwave Radiation

The overall level of concern associated with the use of radiofrequency/microwave radiation in the CFI is low.

The only use of RF/MW is in building 55A, rooms 102 and 104, where MRI machines are used.

Magnetic Fields

The overall level of concern with magnetic fields is very low to moderate.

Magnetic fields are present in building 55A, rooms 102 and 104, associated with the magnetic resonance imaging machines. These are strong fields.

Infectious/Biohazardous Agents

Biohazardous agents and biosafety cabinets are used in this program.

Human Blood/Blood Products

The overall level of concern associated with the use of human blood products is low.

Rooms 116 and 139 in Building 55 uses human blood and blood products. Employees in these areas have been vaccinated for HBV. Other (not specified) non-infectious biological agents are used.

Cell Culture (non-pathogenic)

Cell cultures are not used in the CFI.

Pathogens

Pathogenic organisms are not intentionally used in the CFI.

7. Environmental Biotechnology: Laboratories are located on the 4th Floor of Building 70A. Activities are assessed to be a low level.

Chemical Hazards

Flammable Gases:

Hazard level for flammable gases is low. Only one cylinder of hydrogen is used.

Flammable Liquids:

The level of concern associated with the use of flammable liquids is low.

Reactives:

The level of concern associated with the use of reactives is nil.

Reproductive Toxins:

The overall level of concern associated with the use of reproductive toxins is nil.

Carcinogens:

The overall level of concern associated with the use of carcinogens is low.

Toxic Materials:

The overall level of concern associated with the use of toxic and extremely toxic materials is low.

Physical Agents

Physical agents present are discussed below. All are low hazard activities.

Equipment:

The program uses the following equipment: a PCR in 4461; a gas chromatograph in 4462; a DNA synthesizer (Nucleic Acid Synthesis System) and sequencer in 4462; and an autoclave in 4459. All are low hazard. Compressed gases are located in 4462 and include Nitrogen, Hydrogen, Argon and compressed air). The program also used high voltage electrophoresis located in rooms 4459 and 4461. A centrifuge is located in 4459.

Infectious/Biohazards Agents

Microorganisms occurring in nature are used in the program. A biosafety hood is used and activities are low hazard.

8. General Support: Building 74 contains an Irradiator with a Co-60 sealed source. The equipment is available for use by all the departments. The overall safety is considered low since a thorough safety assessment (AHD) has been conducted and written procedures and mechanical interlocks are in place for operation. In addition, LSD operates the an animal colony utilized by the entire laboratory. The hazards are considered low.

UNCERTAINTIES ABOUT THE WORK

There are no unique uncertainties which will impact hazard identification and selection of applicable and appropriate standards and requirements.

RESOURCE AVAILABILITY AND CONSTRAINTS

No significant changes in LSD resources dedicated to ES&H activities are planned.

Representatives of the LSD (Tony Linard, Bob Springsteen and Scott Taylor) offered the following evaluation of the EH&S Division past and future resources and support:

The need for EH&S resources and support for the coming year should be roughly the same as last year.

LSD judges the EH&S support adequate during the past year.

LSD expects that EH&S will meet LSD needs in the coming year.

The following concerns were raised by LSD:

Current DOE requirements which prevent "decay-in-place" of short lived radioactive materials are not commensurate with the hazard and require unnecessary waste management burdens. If waste standards were more flexible in this regard, the quantity of mixed waste could be reduced substantially permitting more simple waste disposal requirements for hazardous chemical waste.

The following suggestions for improvement were submitted by LSD:

Continued emphasis in improved communication with the EH&S Division's Waste Management Group.

Continued orientation of the EH&S Division's Field Support Group at bench research activities in order to more thoroughly understand and appreciate the relative to low hazard of most research activities. This should result in addressing safety concerns more efficiently.

STAKEHOLDER CONCERNS

There are no stakeholder concerns unique to LSD. LSD has managed, controlled, and permitted (as required) air, water, hazardous, and solid waste streams.


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