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January 9, 2004
 
A Few of NCEM's Greatest Hits

Contributions to fundamental science made by NCEM's staff (presently 15) and users (250 a year) in the last two decades would fill a bookshelf. They include:

  Uli Dahmen and his colleagues discovered that nanoscale lead inclusions in an aluminum matrix assume only specific "magic" shapes and sizes.


  • the abstruse — establishing the "critical voltage effect" for determining submicroscopic parameters in alloys

  • the practical — tracking the odd distribution of elements in indium gallium nitride, gem of the light-emitting diode industry

  • the revolutionary — discovering "magic sizes," "magic shapes," and startling behaviors of nanoparticles in alloys, including Brownian motion of melted inclusions in a solid matrix

  • Telescoping, multiwalled, carbon nanotubes (electron micrograph, background) serve as cylindrical bearings in the world's first nanomotor (inset, Zettl group).
    the futuristic — imaging telescoping carbon nanotubes, now used as a bearing in the world's first nanomotor.

Plus a few just-plain-intriguing mysteries:

  • Uli Dahmen, Ken Westmacott, and colleagues from Case Western Reserve University discovered that a strange "diamond-hexagonal" form of silicon, reported by Russian investigators, formed from the intersection of nanoscale "deformation twins." "There was hope that a new phase of silicon would have interesting electronic properties," says Dahmen. "Not this one. Close but no cigar."

  • Chuck Echer, who worked with many visitors during his 18 years at NCEM, remembers being able to use "a montage of microscopy techniques to absolutely confirm the presence of interstellar diamonds" in carbonaceous meteorites supplied by NASA Ames Research Center.
  •   Carbonaceous meteorites and interstellar dust contain microscopic diamonds that formed as stars condensed.
    Echer was asked by the curator of UC's Lowie Museum of Anthropology to date an Egyptian limestone head. Thought to be from 1600 BCE, traces of orpiment, a paint made from a sulfur-arsenic compound, would mean the head was more recent. "I was able to solve this dating problem using the Analytical Electron Microscope," says Echer, who found no orpiment. "To work on an artifact of that age was a unique forensic investigation into the past."

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